Product ID:FREON TF SOLVENT CLEANER
MSDS Date:01/01/1986
FSC:7045
NIIN:01-276-8761
MSDS Number: BHYDW

Emergency Phone: 201-327-9100

Info Phone: 201-327-9100

Preparer: CHRIS SHERIDAN,TECH.DIR.

Cage: 21994

Telephone: 201-327-5577

Cage: 21994

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:LD 50 ORAL RAT 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH, AND MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, ULNCONSCIOUSNESS OF DEATH.
SKIN/EYE: LIQUID CAN DEFAT TISSUE.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP OR OSHA.
Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY
LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
LIQUID IS NOT CORROSIVE O R AN IRRITANT, BUT CAN CAUSE DEFATTING OF
TISSUE.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS AGENT.

First Aid:INHALATION: REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.IF BREATHING IS DIFFICULT,
GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS. EYE: FLUSH
WITH WATER . SKIN: FLUSH WITH WATER. IF IRRITATIONPRESISTS, GET
MEDICAL ATTENTION. ORAL: GET MEDICAL ATTENTION IMMEDIATELY. DO NOT
INDUCE VOMITING AS THE HAZARD OF ASPIRATING INTO THE LUNGS IS TOO
GREAT.

Flash Point:NONE
Extinguishing Media:AS APPROPIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS. DIKE
SPILL. COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS
FOR RECOVERY OR DISPOSAL. COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS ON REPORTING RELEASES.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE AND KEEP CLOSED.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT WITH EYES, SKIN
OR CLOTHING. TANK-CLEANING PERSONNEL SHOULD USE ONLY FORMAL TANK
ENTRY PROCEDURE BASED ON RECOGNIZED SAFETY PRINCIPLES. EMPTY
CONTAINERS MAY CONTA IN PRODUCT RESIDUES/VAPORS.

Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, USE A
SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR,
APPROVED BY NIOSH.
Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING
SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER.
Protective Gloves:BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS REPEATED
OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:REMOVE AND WASH CLOTHING PROMPTLY UPON
CONTAMINATION.
Supplemental Safety and Health
DO NOT HEAT CONTAINER ABOVE 125F.

HCC:N1
Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:792
Vapor Density:4.9
Spec Gravity:1.48
Evaporation Rate & Reference:0.1 (NO REFERENCE GIVEN)
Solubility in Water:0.1%
Appearance and Odor:COLORLESS LIQUID. SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS (POWDERED ALUMINUM, ZINC, BERYLLIUM,
ETC.)
Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAMES
Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES
FORMING HYDROCHLORIC AND HYDROFLUORIC ACIDS AND POSSIBLE PHOSGENE.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.